Catalysts 01 – Palladium

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The company.
Palladium catalystsfor C-C and C-N coupling reactions.
Product Line Palladium Catalysts. Table of contents.
Complexes with chelating phosphine ligands
N-Heterocyclic carbene complexes (NHC)
Dinuclear complexes
Heterogenized complexes
Palladium Catalyst Kits. Table of contents.
Catalyst Kits
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Gute Chemie. Foreword 1 Gute Chemie. Welcome to abcr. What do you think of when you hear the expression ‚Gute Chemie‘? Does it make you think of top-quality products or people that understand each other really well? Since we set up our company in 1987, we have consistently attempted to combine both. We offer Gute Chemie in the form of more than 400,000 specialty chemicals that we supply to major pharmaceuticals and chemical companies. And we also provide Gute Chemie in terms of our personal service coupled with an extensive network that links our clients, suppliers and partners all around the world. With this brochure, we would like to invite you to experience all the aspects of Gute Chemie. Dr. Jan Schuricht | Managing Director

Gute Chemie. abcr 2 | 3 With abcr, you have access to over 400,000 products from the organic, organometallic and inorganic specialty chemical areas. You can order all of these materials conveniently via our webshop and we keep a large portion of them on stock for you in our logistics centre. Should your desired product not be among them, we will seek out a suitable manufacturer in our international network, or synthesise it in our own laboratories. Working with all sectors Specialisation as standard: our key business fields Pharmaceutical and chemical companies, research labs and universities: our range of products is as diverse as the customers that use them. Applications for abcr’s specialty chemicals include synthesis and catalysis in the life sciences, medicinal chemistry and surface technology areas. We are constantly updating and expanding our product range in line with the progress in research and development. › R&D services: custom synthesis, research projects and abcr product line from our laboratory - Made in Germany › Production: research, process development, scale-up in multi tons scale, syntheses and contract manufacturing from our production facilities - Made in Europe › Bulk business: procurement, scale up and sales of raw materials for your production › Catalogue business: procurement and sales of specialty chemicals, more than 400.000 products easily found in our webshop › Small quantity supply: sample and small quantity sales for products of well-known partners › Services: central warehouse and logistics certified for storage of hazardous materials, daily filling and decanting from grams to tons In our catalogue business you will find following product portfolio: Silanes & Silicones Fluoro Compounds Organometallics Ionic Liquids Monomers & Polymers Biochemistry Reagents Boronic Acids & Esters Specialty Gases Amino Acids Phosphines Catalysts & Ligands Nanomaterials Ceramic Powders Precious Metal Compounds High Purity Metals Rare Earth Compounds Building Blocks Deuterated Compounds Sol-gel Precursor CVD Precursor Solvents

Palladium catalysts for C-C and C-N coupling reactions. abcr offers a wide variety of palladium catalysts which can be applied to C-C and C-N coupling reactions. While early research in cross-coupling reactions also used nickel as a catalyst, the development soon moved on to palladium catalysts. In the meantime, many of the reactions discovered in the 1970’s are among the established organic chemistry synthesis methods. Since that time, palladium catalysts have been used extensively for a broad range of C-C and C-N coupling reactions. For their extensive research in the field of catalysis, the Nobel Prize was awarded to Richard F. Heck, Ei-ichi Negishi and Akira Suzuki in 2010. Heck-Mizoroki reaction: R X + R' [Pd] R R' Stille reaction: R X + R' SnR'' [Pd] R R' + X SnR'' Suzuki-Miyaura reaction: R Br + R' B OH OH [Pd] R R'

Gute Chemie. Products 7 Product Line Palladium Catalysts. Table of contents. Complexes with Non-Phosphine Ligands Complexes with Monodentate Phosphine Ligands Complexes with Chelating Phosphine Ligands N-Heterocyclic Carbene Complexes (NHC) Dinuclear Complexes Heterogenized Complexes Catalyst Kits 9 13 23 27 31 35 37

Gute Chemie. Complexes with Non-Phosphine Ligands 9 Complexes with Non-Phosphine Ligands AB126638 Dichlorobis(acetonitrile)palladium(II); 98% 14592-56-4 AB121374 trans-Bis(benzonitrile)dichloropalladium(II); 99% 14220-64-5 AB144250 Bis(dibenzylideneacetone)palladium(0), Pd(dba)2 32005-36-0 AB401955 trans-Bis(dicyclohexylamine)bis(acetato)palladium(II) 628339-96-8 DAPCy AB400029 Bis[N-(2,5-dimethyl)benzylidene-4-ethyl-3-thiosemi- carbazone-k-N1,S]palladium(II) AB249271 1,2-Bis(phenylsulfinyl)ethanepalladium(II) acetate; 858971-43-4 98%, Christina White Catalyst AB268578 Bis(2,2,6,6-tetramethyl-3,5-heptanedionato) 15214-66-1 palladium(II); 98% [Pd(TMHD)2] Cl N Pd N Cl Cl N Pd N Cl O Pd O H N O PdO O O N H HN S N H N Pd N H N S NH O O S S Pd O O O O O O Pd O O abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

10 AB331627 Bromo[[1,3-bis[(4S,5S)-1-benzoyl-4,5-diphenyl-2- 1242081-29-3 imidazolin-2-yl]benzene]palladium(II)] AB304015 Chloro(methyl)(1,5-cyclooctadiene)palladium(II); 98% 63936-85-6 AB304262 Cyclopentadienyl[(1,2,3-h)-1-phenyl-2-propenyl] 105333-10-6 palladium(II); 98% AB201547 Dichloro(cycloocta-1,5-diene)palladium(II), Pd 37.3% 12107-56-1 AB249104 Dichloro(norbornadiene)palladium(II); 99% 12317-46-3 AB249201 cis-Dichloro(N,N,N‘,N‘-tetramethylethylenediamine) 14267-08-4 palladium(II); 99% AB252730 cis-Dimethyl(N,N,N‘,N‘-tetramethylethylenediamine) 113822-11-0 palladium(II), 99% AB121377 Palladium(II) acetate; 98% 3375-31-3 AB181999 Palladium(II) acetate; 99% (99.95% Pd) 3375-31-3 Gute Chemie O N O N N N Pd Br Pd Cl Pd Pd Cl Cl Pd Cl Cl N N Pd Cl Cl N N Pd O O Pd O O O O Pd O O

Gute Chemie. Complexes with Non-Phosphine Ligands 11 AB211090 Palladium(II) acetate, trimer; 99.98% (metals basis), 3375-31-3 Pd 47% AB121378 Palladium(II) acetylacetonate; 99% 14024-61-4 AB304016 Palladium(II) benzoate; 99% 3375-32-4 AB304142 Palladium(II) hexafluoroacetylacetonate; 95% 64916-48-9 AB121384 Palladium(II) trifluoroacetate; 97% 42196-31-6 AB268532 Palladium(II) trimethylacetate; 98% 106224-36-6 AB105577 Tetrakis(acetonitrile)palladium(II) tetrafluoroborate; 21797-13-7 99% O O Pd O O 3 O O Pd O O O O Pd O O F F F F F F O O Pd O O F F F F F F O O Pd O O F F F F F F O O Pd O O - BF4 N N Pd2+ N N - BF4 abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

Gute Chemie. Complexes with Monodentate Phosphine Ligands 13 Complexes with Monodentate Phosphine Ligands AB137301 Benzylbis(triphenylphosphine)palladium(II) chloride; 22784-59-4 96% AB401964 Bis{[4-(N,N-dimethylamino)phenyl]di-t-butylphos- 1233717-68-4 phino}palladium(0); min. 98% Pdamphos AB264104 Bis(di-tert-butyl-phenylphosphine)palladium(0), Pd 52359-17-8 19.3% AB144669 Bis(methyldiphenylphosphine)palladium(II) dichloride; 52611-08-2 96% AB264107 Bis[1,2,3,4,5-pentaphenyl-1‘-(di-t-butylphosphino) 565441-56-7 ferrocene]palladium(0), Pd 7.0% AB134604 Bis(tri-tert-butylphosphine)palladium(0); 98% 53199-31-8 P Cl Pd P N P P Pd N P Pd P Cl P Pd P Cl Ph Ph Ph Ph Fe Ph P Pd P Ph Fe Ph Ph Ph Ph P Pd P abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

14 AB123786 Bis(tricyclohexylphosphine)palladium(0); 98% 33309-88-5 AB264079 Bis(tri-o-tolylphosphine)palladium(0); 99%, Pd 14.9% 69861-71-8 AB268448 Chloro{[BrettPhos][2-(2-aminoethylphenyl] palladium(II)]}/[BrettPhos] admixture (molar PdP/P = 1:1) AB268518 Chloro{[t-butylXPhos][2-(2-aminoethylphenyl] palladium(II)}/[t-butylXPhos] admixture (molar PdP/P = 1:1) AB255538 Chloro(2-di-tert-butylphosphino-2‘,4‘,6‘-triisopropyl- 1142811-12-8 1,1‘-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II), t-BuXPhos Palladacycle; 97% AB355950 Chloro(2-dicyclohexylphosphino-2‘,6‘-diisopropoxy- 1375325-68-0 1,1‘-biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), RuPhos Palladacycle; 98% AB255541 Chloro(2-dicyclohexylphosphino-2‘,6‘-diisopropoxy- 1028206-60-1 1,1‘-biphenyl)[2-(2-aminoethylphenyl)]palladium(II), methyl-t-butylether adduct, RuPhos Palladacycle, methyl-t-butylether adduct; 98% Gute Chemie P Pd P P Pd P P Pd Cl N H H O O P Pd Cl N H H O O P Pd Cl N H H

Gute Chemie. Complexes with Monodentate Phosphine Ligands 15 AB355949 Chloro(2-dicyclohexylphosphino-2‘,6‘-dimethoxy-1,1‘- 1375325-64-6 biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl) palladium(II), SPhos Palladacycle; 98% AB254623 Chloro(2-dicyclohexylphosphino-2‘,6‘-dimethoxy-1,1‘- 1028206-58-7 biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl- t-butylether adduct, SPhos Palladacycle; 98% AB355951 Chloro(2-dicyclohexylphosphino-3,6-dimethoxy-2‘,4‘,6‘- 1451002-39-3 triisopropyl-1,1‘-biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl) palladium(II), BrettPhos Palladacycle; 98% AB255542 Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy- 1148148-01-9 2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl][2-(2-aminoethyl)phe- nyl]palladium(II), BrettPhos Palladacycle; min. 98% AB400820 Chloro[2-(dicyclohexylphosphino)-2‘-(N,N- dimethylamino)-1,1‘-biphenyl](2‘-amino-1,1‘-biphenyl- 2-yl)palladium(II), min. 98% [DavePhos Palladacycle] AB355948 Chloro(2-dicyclohexylphosphino-2‘,4‘,6‘-triisopropyl- 1310584-14-5 1,1‘-biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), XPhos Palladacycle; 98% AB250862 Chloro(2-dicyclohexylphosphino-2‘,4‘,6‘-triisopropyl- 1028206-56-5 1,1‘-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II), methyl t-butyl ether adduct, XPhos Palladacycle; 98% O O P Pd Cl N H H O O P Pd Cl N H H O O P Pd Cl N H H O O P Pd Cl N H H N P Pd Cl N H H P Pd Cl N H H P Pd Cl N H H abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

16 AB400823 Chloro{[4-(N,N-dimethylamino)phenyl]di-tert-butyl- phosphino}(2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), min. 98% [amphos Palladacycle] AB400827 Chloro[9,9-dimethyl-4,5-bis(diphenylphosphino) 1375325-77-1 xanthene][2‘-amino-1,1‘-biphenyl]palladium(II) dichlo- romethane adduct, min. 98% AB143941 Chloro(di-2-norbornylphosphino)(2‘-dimethylamino- 359803-53-5 1,1‘-biphenyl-2-yl)palladium; 97% AB152508 Chloro(di-2-norbornylphosphino)(2-dimethylaminofer- 614753-51-4 rocen-1-yl)palladium(II); 97% AB256316 Chloro{[RuPhos][2-(2-aminoethylphenyl]palladium(II)}/ [RuPhos] admixture (molar PdP/P = 1:1) AB268483 Chloro{[S-Phos][2-(2-aminoethylphenyl]palladium(II)}/ [S-Phos] admixture (molar PdP/P = 1:1) AB268482 Chloro{[X-Phos][2-(2-aminoethylphenyl]palladium(II)}/ [X-Phos] admixture (molar PdP/P = 1:1) AB105576 Diacetatobis(triphenylphosphine)palladium(II); 99% 14588-08-0 Gute Chemie N P Pd Cl N H H P O P Pd Cl N H H Cl Pd P H N Fe N Pd Cl P H P O Pd O P O O

Gute Chemie. Complexes with Monodentate Phosphine Ligands 17 AB203380 trans-Dibromobis(triphenylphosphine)palladium(II), Pd 22180-53-6 13.4% AB252914 Dibromobis(tri-o-tolylphosphine)palladium(II), Pd 12% 24554-43-6 AB401963 Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t- 887919-35-9 butylphosphino}palladium(II); min. 98% Pdamphos AB426007 Dichlorobis(di-t-butylphenylphosphino)palladium(II); 34409-44-4 99% AB123788 trans-Dichlorobis(tricyclohexylphosphine)palladium(II); 29934-17-6 99% AB208988 trans-Dichlorobis(triethylphosphine)palladium(II); 99% 28425-04-9 P Pd Br Br P P Br Pd Br P N Cl P Pd P Cl N Cl P Pd P Cl Cl P Pd P Cl Cl P Pd P Cl abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

18 AB116703 trans-Dichlorobis(triphenylphosphine)palladium(II); 13965-03-2 99% AB209725 trans-Dichlorobis(triphenylphosphine)palladium(II), 13965-03-2 Premion®; 99.95% (metals basis), Pd 14.7% AB123789 trans-Dichlorobis(tri-o-tolylphosphine)palladium(II); 40691-33-6 95% AB252912 trans-Dichlorobis(tri-o-tolylphosphine)palladium(II); 40691-33-6 98% Cl P Pd P Cl Cl P Pd P Cl P Cl Pd Cl P P Cl Pd Cl P AB355953 Methanesulfonato{2-bis[3,5-di(trifluoromethyl) phenylphosphino]-3,6-dimethoxy-2‘-4‘-6‘-triisopropyl- 1,1‘-biphenyl](2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), JackiePhos Palladacycle; 98% AB400826 Methanesulfonato(di-tert-butylneopentylphosphine) (2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), min. 98% Gute Chemie O F3C CF3 O F3C P Pd O N H H S O CF3 O P Pd O N H H S O O

Gute Chemie. Complexes with Monodentate Phosphine Ligands 19 AB391074 Methanesulfonato(2-(di-tert-butylphosphino)-3,6- dimethoxy-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl)(2‘-amino- 1,1‘-biphenyl-2-yl)palladium(II), t-butylBrettPhos Palladacycle; 98% O O P Pd O N SO O H H AB400822 Methanesulfonato(2-(di-tert-butylphosphino)-3-me- thoxy-6-methyl-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl) (2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), min. 98% [RockPhos Palladacycle] AB355952 Methanesulfonato(2-di-tert-butylphosphino-2‘,4‘,6‘- 1447963-75-8 triisopropyl-1,1‘-biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl) palladium(II), t-BuXPhos Palladacycle; 98% AB333920 Methanesulfonato(2-dicyclohexylphosphino-2‘,6‘- 1445085-77-7 diisopropoxy-1,1‘-biphenyl)(2-amino-1,1‘-biphenyl-2-yl) palladium(II), RuPhos Palladacycle; 98% AB333921 Methanesulfonato(2-dicyclohexylphosphino-2‘,6‘- 1445085-82-4 dimethoxy-1,1‘-biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl) palladium(II), SPhos Palladacycle; 98% O P Pd O S O O N H H P Pd N O H H O S O O O P Pd O N H H S O O O O P Pd O N H H S O O AB333923 Methanesulfonato(2-dicyclohexylphosphino-3,6-dime- 1470372-59-8 thoxy-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl)(2‘-amino-1,1‘- biphenyl-2-yl)palladium(II), BrettPhos Palladacycle; 98% O O P Pd O N H H S O O abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

20 AB400821 Methanesulfonato[2-(dicyclohexylphosphino)-2‘- 1445085-87-9 (N,N-dimethylamino)-1,1‘-biphenyl](2‘-amino-1,1‘- biphenyl-2-yl)palladium(II) CH2Cl2 adduct, min. 98% [DavePhos Palladacycle] AB400825 Methanesulfonato{(R)-(-)-1-[(S)-2- (dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butyl- phosphine}(2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), Bruno Palladacycle; min. 98% AB333922 Methanesulfonato(2-dicyclohexylphosphino-2‘,4‘,6‘- 1445085-55-1 triisopropyl-1,1‘-biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl) palladium(II), XPhos Palladacycle; 98% AB400824 Methanesulfonato{[4-(N,N-dimethylamino)phenyl] di-tert-butylphosphino}(2‘-amino-1,1‘-biphenyl-2-yl) palladium(II), min. 98% [amphos Palladacycle] AB400828 Methanesulfonato[9,9-dimethyl-4,5- 1445085-97-1 bis(diphenylphosphino)xanthene][2‘-amino-1,1‘-biphe- nyl]palladium(II) dichloromethane adduct, min. 98% AB268585 Palladium(II) acetate/2-dicyclohexylphosphino- 2‘,6‘-dimethoxy-1,1-biphenyl/potassium phosphate admixture Gute Chemie N P Pd O S O O N H H Fe P P Pd O N H H S O O P Pd O S O O N H H N P Pd O S O O N H H P O P Pd O SO O N H H

Gute Chemie. Complexes with Monodentate Phosphine Ligands 21 AB116702 Tetrakis(triphenylphosphine)palladium(0); 99.9% 14221-01-3 P P Pd P P AB387146 Tris[tris(3,5-bis(trifluoromethyl)phenyl)phosphine] 1130784-80-3 palladium(0) CF3 CF3 CF3 CF3 F3C P CF3 F3C P CF3 F3C CF3 CF3 Pd F3C CF3 CF3 F3C P CF3 F3C CF3 abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

Gute Chemie. Complexes with Chelating Phosphine Ligands 23 Complexes with Chelating Phosphine Ligands AB148086 Acetato(2‘-di-tert-butylphosphino-1,1‘-biphenyl-2-yl) 577971-19-8 palladium(II) AB102768 Bis[1,2-bis(diphenylphosphino)ethane]palladium; 31277-98-2 98% AB155745 [P,P‘-1,3-Bis(diisopropylphosphino)propane][P-1,3- 123333-45-9 bis(di-i-propylphosphino)propane]palladium(0); 98% AB252915 Dibromo[1,1‘-bis(diphenylphosphino)ferrocene] 12468-93-5 palladium(II); Pd 12.9% AB249242 Dichloro[1,1‘-bis(di-tert-butylphosphino)ferrocene] 95408-45-0 palladium(II); 99% P O Pd O P P Pd P P P P Pd P P Fe P P Pd Br Br Fe P P Pd Cl Cl abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

24 AB268580 Dichloro[1,1‘-bis(dicyclohexylphosphino)ferrocene] 917511-90-1 palladium(II), dichloromethane adduct; 99% AB268484 Dichloro[1,1‘-bis(diisopropylphosphino)ferrocene] 215788-65-1 palladium (II); 99% AB268582 Dichloro[(R)-(+)-2,2‘-bis(diphenylphosphino)-1,1‘- 115826-95-4 binaphthyl]palladium(II); 98% (R-BINAP) AB268582 Dichloro[(R)-(+)-2,2‘-bis(diphenylphosphino)-1,1‘- 115826-95-4 binaphthyl]palladium(II); 98% AB268583 Dichloro[(S)-(-)-2,2‘-bis(diphenylphosphino)-1,1‘- 127593-28-6 binaphthyl]palladium(II); 98% (S-BINAP) AB401961 Dichloro[1,4-bis(diphenylphosphino)butane] 29964-62-3 palladium(II); 99% AB121375 Dichloro[1,2-bis(diphenylphosphino)ethane] 19978-61-1 palladium(II); 98% Gute Chemie Fe Fe P P P P Pd Cl Cl Pd Cl Cl P P Pd Cl Cl P P Pd Cl Cl P P Pd Cl Cl P P P P Pd Cl Cl Pd Cl Cl

Gute Chemie. Complexes with Chelating Phosphine Ligands 25 AB152323 Dichloro[1,1‘-bis(diphenylphosphino)ferrocene] 72287-26-4 palladium(II); 99.9% AB252911 Dichloro[1,1‘-bis(diphenylphosphino)ferrocene] 851232-71-8 palladium(II), complex with acetone; Pd 13.0-15.0% AB127390 Dichloro[1,1‘-bis(diphenylphosphino)ferrocene] 95464-05-4 palladium(II) dichloromethane adduct; 99% AB252913 Dichloro[bis(diphenylphosphinophenyl)ether] 205319-06-8 palladium(II), Pd 14.8% AB206106 Dichloro[bis(1,3-diphenylphosphino)propane] 59831-02-6 palladium(II) AB268581 Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino) 205319-10-4 xanthene]palladium(II); 98% AB268584 Palladium(II) acetate/1,1‘-bis(di-t-butylphosphino) ferrocene/potassium phosphate admixture Fe P P Pd Cl Cl Fe Fe P P P P Pd Cl Cl Pd Cl Cl O Cl P Pd P Cl Pd Cl Cl O Pd Cl Cl abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

Gute Chemie. N-Heterocyclic Carbene Complexes (NHC) 27 N-Heterocyclic Carbene Complexes (NHC) AB172138 Allylchloro[1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroi- 478980-01-7 midazol-2-ylidene]palladium(II); 97% AB148053 Allylchloro[1,3-bis(2,6-diisopropylphenyl)imidazol- 478980-03-9 2-ylidene]palladium(II); 98% AB249117 Allylchloro[1,3-bis(2,4,6-trimethylphenyl)imidazol- 478980-04-0 2-ylidene]palladium(II); 98% AB333919 N,N‘-[Bis(2,6-dimethylphenyl)-1,3-dimethyl-1,3-propa- 1224879-40-6 nediylidene](methyl)(triethylphosphine)palladium(II); 97% AB153482 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene(1,4- 649736-75-4 naphthoquinone)palladium(0) dimer; 96% AB153483 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene(1,4- 467220-49-1 naphthoquinone)palladium(0) dimer; 96% Cl Pd Cl Pd N N N N Cl Pd N N N N Pd PEt3 O N N Pd O O Pd N N O O N N Pd O O Pd N N O abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

28 AB261408 Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylide- 1228009-69-5 ne](acetanilide)palladium(II)]; 98% AB261405 Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylide- 930796-10-4 ne](N,N-dimethylbenzylamine)palladium(II)]; 97% AB261411 Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylide- ne](4‘-methoxyacetanilide)palladium(II)]; 98% AB261410 Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol- 1093348-08-3 2-ylidene](N,N-dimethyl-3,5-dimethoxybenzylamine) palladium(II)], SingaCycle™-A2; 98% AB261401 Chloro[(1,3-dimesitylimidazol-2-ylidene)(N,N-dimethyl- 1058661-78-1 benzylamine)palladium(II)], SingaCycle™-E1; 98% AB200507 Chloro[(1,2,3-h)-3-phenyl-2-propenyl][1,3-bis(2,6- 884879-24-7 diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene] palladium(II); 97% Gute Chemie Cl Pd O NH Cl Pd N N N N N N N Cl Pd O NH O Cl Pd N N N O O Cl Pd N N N Cl Pd N N

Gute Chemie. N-Heterocyclic Carbene Complexes (NHC) 29 AB252729 Chloro[(1,2,3-h)-3-phenyl-2-propenyl][1,3-bis(2,6-diiso- 884879-23-6 propylphenyl)imidazol-2-ylidene]palladium(II); 97% AB357252 Dichloro[1,3-bis(2,6-diisopropylphenyl)-2-imidazolidi- 927706-57-8 nylidene](3-chloropyridine)palladium(II) Cl Pd N N Cl N N Cl Pd N Cl abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

Gute Chemie. Dinuclear Complexes 31 Dinuclear Complexes AB111899 Allylpalladium chloride dimer; 99% 12012-95-2 AB400031 Bis[µ-chloro-{N-(2-thienylmethylene)-4-ethyl-3- thiosemicarbazone-k-N1,S}palladium(II)] AB400030 Bis[µ-chloro-{N-(2-thienylmethylene)-4-methyl-3- thiosemicarbazone-k-N1,S}palladium(II)] AB131617 Bis(2-methylallyl)palladium chloride dimer; 98% 12081-18-4 AB333925 (2‘-Amino-1,1‘-biphenyl-2-yl) 1435520-65-2 methanesulfonatopalladium(II) dimer; 98% AB355954 Chloro(2‘-amino-1,1‘-biphenyl-2-yl)palladium(II) dimer; 847616-85-7 98% AB127388 Crotylpalladium chloride dimer; 99% 12081-22-0 AB128853 trans-Di(µ-acetato)bis[o-(di-o-tolylphosphino)benzyl] 172418-32-5 dipalladium(II); 97% Pd Cl Cl Pd S H N N Pd S HN Cl Cl NH N S S N Pd H S H N N Pd S HN Cl Cl NH N S S N Pd H

32 AB204511 Di-µ-bromobis(tri-tert-butylphosphine)dipalladium(I) 185812-86-6 AB261530 Di-µ-chlorobis[5-chloro-2-[(4-chlorophenyl)(hydroxyimi- 287410-78-0 no)methyl]phenyl]palladium(II) dimer AB333924 Di-µ-chlorobis{2-[(dimethylamino)methyl]phenyl} 18987-59-2 dipalladium; 99% AB268579 Di-µ-chlorobis[(1,2,3-h)-1-phenyl-2-propenyl] 12131-44-1 dipalladium(II); 98% AB170713 Dichloro(chlorodi-tert-butylphosphine)palladium(II) 386706-33-8 dimer AB170796 Dichloro(chlorodicyclohexylphosphine)palladium(II) dimer AB249105 Dichloro(di-µ-chloro)bis[1,3-bis(2,6-diisopropylphenyl) 444910-17-2 imidazol-2-ylidene]dipalladium(II); 97% Gute Chemie P Pd Br Br Pd P Cl Cl Pd N Cl Cl N Pd Cl Cl N Pd Pd Cl Cl N Pd Cl Cl Pd Cl P Pd Cl Cl Cl Pd Cl P Cl Cl P Pd Cl Cl Cl Pd Cl P Cl N Pd N Cl Cl Cl Pd Cl N N

Gute Chemie. Dinuclear Complexes 33 AB355955 Tris[di(4-acetoxybenzylidene)acetone]dipalladium(0) 1196118-15-6 O di(4-acetoxybenzylidene)acetone adduct; 97% AB119106 Tris(dibenzylideneacetone)dipalladium(0); 20-23% Pd 51364-51-3 AB180063 Tris(dibenzylideneacetone)dipalladium(0) chloroform 52522-40-4 adduct; 97% Pd2 O O O O 3 O O Pd2 3 Pd2 3 abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

Gute Chemie. Heterogenized Complexes 35 Heterogenized Complexes AB144294 Di(acetato)(dicyclohexylphenylphosphine)palladium(II); (5% Pd) polymer-bound, 672310-94-0 FibreCat TM AB249195 Dibenzylideneacetonepalladium(0) phosphaadamantane ethyl Silica AB249196 Triphenylphosphinepalladium(II) dichloride phosphaadamantane ethyl Silica AB260116 Tris(triphenylphosphin)-palladium(0)-triphenylphosphine polystyrene (100-200 mesh, 0.1-0.15 mmol/g) abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

Gute Chemie. Catalyst Kits 39 Catalyst Kits AB 255576 Buchwald Palladacycle Precatalyst Kit 1 for aromatic carbon-heteroatom bond formation, Suzuki coupling & Negishi cross-coupling; contains five chloro-2-aminoethylphenyl palladacycles The Kit contains samples of AB250862 Chloro(2-dicyclohexylphosphino-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl) [2-(2-aminoethyl)phenyl]palladium(II), methyl t-butyl ether adduct, XPhos Palladacycle; 98% AB254623 Chloro(2-dicyclohexylphosphino-2‘,6‘-dimethoxy-1,1‘-biphenyl) [2-(2-aminoethylphenyl)]palladium(II) methyl-t-butylether adduct, SPhos Palladacycle; 98% AB255538 Chloro(2-di-tert-butylphosphino-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl) [2-(2-aminoethyl)phenyl]palladium(II), t-BuXPhos Palladacycle; 97% AB255541 Chloro(2-dicyclohexylphosphino-2‘,6‘-diisopropoxy-1,1‘-biphenyl)[2-(2-aminoethylphenyl)] palladium(II), methyl-t-butylether adduct, RuPhos Palladacycle, methyl-t-butylether adduct; 98% AB255542 Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl] [2-(2-aminoethyl)phenyl]palladium(II), BrettPhos Palladacycle; min. 98% AB 333979 Buchwald Palladacycle Precatalyst Kit 2 contains eight methanesulfonato palladacycles The Kit contains samples of AB333920 Methanesulfonato(2-dicyclohexylphosphino-2‘,6‘-diisopropoxy-1,1‘-biphenyl) (2-amino-1,1‘-biphenyl-2-yl)palladium(II), RuPhos Palladacycle; 98% AB333921 Methanesulfonato(2-dicyclohexylphosphino-2‘,6‘-dimethoxy-1,1‘-biphenyl) (2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), SPhos Palladacycle;98% AB333922 Methanesulfonato(2-dicyclohexylphosphino-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl) (2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), XPhos Palladacycle; 98% AB333923 Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2‘,4‘,6‘-triisopropyl-1,1‘- biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), BrettPhos Palladacycle; 98% AB355952 Methanesulfonato(2-di-tert-butylphosphino-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl)(2‘-amino- 1,1‘-biphenyl-2-yl)palladium(II), t-BuXPhos Palladacycle; 98% AB355953 Methanesulfonato{2-bis[3,5-di(trifluoromethyl)phenylphosphino]-3,6-dimethoxy-2‘-4‘-6‘- triisopropyl-1,1‘-biphenyl](2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), JackiePhos Palladacycle; 98% AB391074 Methanesulfonato(2-(di-tert-butylphosphino)-3,6-dimethoxy-2‘,4‘,6‘-triisopropyl-1,1‘- biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), t-butylBrettPhos Palladacycle; 98% AB400822 Methanesulfonato(2-(di-tert-butylphosphino)-3-methoxy-6-methyl-2‘,4‘,6‘- triisopropyl-1,1‘-biphenyl)(2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), RockPhos Palladacycle; min. 98% AB 355933 Buchwald Palladacycle Precatalyst Kit 3 contains four chloro-2‘-amino-1,1‘-biphenyl-2-yl palladacycles) The Kit contains samples of AB355948 Chloro(2-dicyclohexylphosphino-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl)(2‘-amino-1,1‘- biphenyl-2-yl)palladium(II), XPhos Palladacycle; 98% AB355949 Chloro(2-dicyclohexylphosphino-2‘,6‘-dimethoxy-1,1‘-biphenyl)(2‘-amino-1,1‘- biphenyl-2-yl) palladium(II), SPhos Palladacycle; 98% AB355950 Chloro(2-dicyclohexylphosphino-2‘,6‘-diisopropoxy-1,1‘-biphenyl)(2‘-amino-1,1‘- biphenyl-2-yl)palladium(II), RuPhos Palladacycle; 98% AB355951 Chloro(2-dicyclohexylphosphino-3,6-dimethoxy-2‘,4‘,6‘-triisopropyl-1,1‘-biphenyl) (2‘-amino-1,1‘-biphenyl-2-yl)palladium(II), BrettPhos Palladacycle; 98% abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

40 AB 127009 Palladium Kit contains 7 different Pd catalysts for a variety of catalytic organic transformations The Kit contains samples of AB111899 Allylpalladium chloride dimer; 99% AB113726 Tris(dibenzylideneacetone)dipalladium (0) chloroform adduct; 99% AB116702 Tetrakis(triphenylphosphine)palladium(0); 99.9% AB119106 Tris(dibenzylideneacetone)dipalladium(0); 20-23% Pd AB121374 trans-Bis(benzonitrile)dichloropalladium(II); 99% AB121377 Palladium(II) acetate; 98% AB121380 Palladium(II) chloride; 99.9%, ca. 60% Pd AB 130653 Phosphine Ligand Kit for Palladium-Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond Formation contains 9 different phosphine ligands The Kit contains samples of AB111749 Tris-(o-tolyl)phosphine; 98% AB113536 1,1‘-Bis(diphenylphosphino)ferrocene; 99% AB121627 Tri-2-furylphosphine; 98% AB127398 racemic-2,2‘-Bis(diphenylphosphino)-1,1‘-binaphthyl; 98% BINAP AB130265 Bis(2-diphenylphosphinophenyl)ether; 98% AB130657 Tris(2,4-di-t-butylphenyl)phosphite; 98% AB130685 2-(Di-t-butylphosphino)biphenyl; 99% AB143896 Tri-t-butylphosphonium tetrafluoroborate; 99% AB146603 Di-t-butylmethylphosphonium tetrafluoroborate; 99% Gute Chemie

Gute Chemie. Greater diversity, choice and value. Make use of our e-papers to quickly and easily browse through our catalogues and flyers and search for products. All products listed in the e-papers are linked to the respective product detail page within our website where you will find further information. We can also send the catalogues and flyers by mail. Enzyme-based Catalysis Life Science Drug Design Silicon Compounds Organozinc Reagents Fluorinated Compounds Catalysts Ligands Freaky Amino Acids Fluorinated Isoquinolines Find 400,000 specialty chemicals in our webshop www.abcr.com abcr GmbH Germany +49 721 95061-0 info@abcr.com abcr swiss AG +41 41 7201882 info@abcr-swiss.ch abcr france SAS +33 4 7291 3100 info@abcr-france.fr abcr IRL Ltd. +353 56 7738971 info@abcr-irl.ie abcr UK Ltd. +44 161 8187062 info@abcr-uk.com LLC ABCR CHEMI RUS +7 495 9664181 info@abcr-russia.ru References(1) (a) Matsui, T., et. al. J. Med. Chem. 1992, 35, 3307; (b) Sunderland, P. T, et. al. J. Med. Chem. 2011, 54, 2049; (c) Busby, S. A., et. al. Chem Biol. 2011, 6, 618. (2) Frackenpohl, J., et. al., Patent WO2013004652 A1.NOR3HR1R2R4HReferences(1) (a) Matsui, T., et. al. J. Med. Chem. 1992, 35, 3307; (b) Sunderland, P. T, et. al. J. Med. Chem. 2011, 54, 2049; (c) Busby, S. A., et. al. Chem Biol. 2011, 6, 618. (2) Frackenpohl, J., et. al., Patent WO2013004652 A1.(R,R)-Catalyst (35 mol-%)MnO2 (3 eq.), Li2CO3 (2 eq.)PhCF3, 115 °C, 24 hup to 86% yield) (2 eq.)NNOSO2RHHNNHSO2Rup to 94% yield(S,S)-ligand (8 mol-%)THF, diglyme-20°CRalkylNN)(S,S)-ligand (8 mol-%)R1CF3R1+F3C(S,S)-ligand (8 mol-%THF, diglym-20°alkylCoI2 (10 mol-%)(S,S)-ligand (12 mol-%)THF, -80°CArylMgBrROup to 96% yield)ROArylalkylCo(S,S)-ligand (12 mol-%THF, -80°CROBralkyl+ArylMgBrup to 96% yieldONNOCuTfOOTfNNO(R,R)-Catalyst (35 mol-%)MnO2 (3 eq.), Li2CO3 (2 eq.)PhCF3, 115 °C, 24 hup to 86% yield) (2 eq.)NNOSO2RHHNNHSO2RR2(DME)NiCl2 (5 mol-%)(S,S)-ligand (6 mol-%)TMEDA (1.6 eq.)THF, 0°Cup to 94% yieldR1) (6 mol-%)R1FFNOR2R2ZnClR1+BrFFNOR2R2(DME)NiCl(S,S)-ligandTMEDA (1.6 eq.)THF, 0°Cup to 94% yield(DME)NiCl2 (6 mol-%)(S,S)-ligand (8 mol-%)THF, diglyme-20°CRalkylONNO)(S,S)-ligand (8 mol-%)R1alkylCF3ZnClR1+F3C(DME)NiCl(S,S)-ligand (8 mol-%THF, diglym-20°XalkylCoI2 (10 mol-%)(S,S)-ligand (12 mol-%)THF, -80°CArylMgBrROup to 96% yield)ROArylalkylCo(S,S)-ligand (12 mol-%THF, -80°CROBralkyl+ArylMgBrup to 96% yieldNNO(S,S)-ligandONNOCuTfOOTfNNOLife ScienceNew Chirals for Drug DesignNNNN01Life ScienceNew Chirals for Drug DesignNNNN01New Organozinc Reagents for Organic Synthesis01New Organozinc Reagents for Organic Synthesis01Commercial Organofunctional Silanes for Diagnostics and Separation01Commercial Organofunctional Silanes for Diagnostics and Separation0101Available in bulk quantities Fluoro Organic Intermediates01Available in bulk quantities Fluoro Organic Intermediates

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