Metall-01 – Organozinc

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New Organozinc Reagents for Organic Synthesis.
Highly Reactive Zinc Solution.
Organozinc Reagents
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Gute Chemie Foreword 1 Gute Chemie. Welcome to abcr. What do you think of when you hear the expression ‚Gute Chemie‘? Does it make you think of top-quality products or people that understand each other really well? Since we set up our company in 1987, we have consistently attempted to combine both. We offer Gute Chemie in the form of more than 400,000 specialty chemicals that we supply to major pharmaceuticals and chemical companies. And we also provide Gute Chemie in terms of our personal service coupled with an extensive network that links our clients, suppliers and partners all around the world. With this brochure, we would like to invite you to experience all the aspects of Gute Chemie. Dr. Jan Schuricht | Managing Director

Gute Chemie New Organozinc Reagents 2 | 3 Gute Chemie. New Organozinc Reagents for Organic Synthesis. Organozinc reagents can be applied in cross coupling reactions with many electrophiles in the presence of Cu(I) or Pd(0) catalysts. The organozinc compounds can be prepared from highly reactive zinc and aromatic, heteroaromatic, vinylic, or aliphatic halides by insertion of the metal into the carbon-halogen bond. As a great advantage over Grignard or organolithium reagents, organozinc compounds tolerate functional groups like esters and nitriles. Br Br Zn O O O O Zn Br F Zn Br Br Zn S N Organozinc reagents to give react with Acid chlorides Ketones α,β-Unsaturated ketones Saturated ketones enynes Aryl halides Substituted aromatics Allylic or vinylic halides Alkynes Allylic or vinylic aromatics or aliphatics Substituted dienes (Michael addition products) Aldehydes Alcohols Literature on the preparation and application of organozinc reagents: › L. Zhu, R. Wehmeyer, R. Rieke, J. Org. Chem., 1991, 56, 1445. › R. D. Rieke, M. V. Hanson, Chapter 2 in “Practical Approach in Organozinc Reagents”, edited by P. Knochel and P. Jones (Oxford University Press) › A. Guijarro, D. M. Rosenberg, R. D. Rieke, J. Am. Chem. Soc., 1999, 121, 4155. › R. D. Rieke, M. V. Hanson, Tetrahedron, 1997, 53, 1925.

Gute Chemie. New Organozinc Reagents 5 Gute Chemie. Highly Reactive Zinc Solution. AB 391308 Rieke® Zinc 2.5g in 100ml of THF 7440-66-6 AB 391309 Rieke® Zinc 10g in 100ml of THF 7440-66-6 AB 391310 Rieke® Zinc 50g in 500ml of THF 7440-66-6 AB 391311 Rieke® Zinc 100g in 1000ml of THF 7440-66-6 abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

Gute Chemie. New Organozinc Reagents 7 Organozinc Reagents AB 361379 4-Acetoxybutylzinc bromide, 0.5M in THF 737797-42-1 AB 361378 5-Acetoxypentylzinc bromide, 0.5M in tetrahydrofuran 737797-40-9 AB 361392 2-Acetoxyphenylzinc iodide, 0.5M in tetrahydrofuran AB 361393 3-Acetoxyphenylzinc iodide, 0.5M in tetrahydrofuran 1227941-06-1 AB 361394 4-Acetoxyphenylzinc iodide, 0.5M in tetrahydrofuran AB 356035 1-Adamantylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 312624-15-0 AB 356111 2-Adamantylzinc bromide, 0.5M in THF 171860-65-4 AB 350881 Allylzinc bromide, 0.5M in THF 18925-10-5 AB 361483 2-Benzothiazolylzinc bromide, 0.5M in tetrahydrofuran 1618666-29-7 AB 348814 Benzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 62673-31-8 Br Zn AB 361333 (2-Biphenyl)methylzinc bromide, 0.5M in tetrahydrofuran 312624-17-2 O O Zn Br O O Br Zn I Zn O O I I Zn O O O O Zn H H CH2 H2 C H2 C H Br Zn Zn Br Zn Br Br Zn N S Br Zn abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

8 AB 348432 4-Biphenylzinc bromide, 0.5M in THF 312693-44-0 AB 361387 2-Biphenylzinc iodide, 0.5M in tetrahydrofuran 738580-35-3 AB 356144 2-Bromobenzylzinc bromide, 0.5M in THF 307496-27-1 Br Zn Zn I Br Br Zn AB 356234 3-Bromobenzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 307496-31-7 Br Zn Br AB 356138 4-Bromobenzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 115055-85-1 AB 361456 3-Bromo-5-ﬂuorobenzylzinc bromide, 0.5M in tetrahydrofuran AB 361473 4-Bromo-2-ﬂuorobenzylzinc bromide, 0.5M in tetrahydrofuran AB 353338 4-Bromo-2-ﬂuorophenylzinc iodide, 0.5M in THF 352530-44-0 AB 229381 4-Bromo-3-ﬂuorophenylzinc iodide; 0.5 M in THF 352525-65-6 AB 361485 5-Bromo-2-ﬂuorophenylzinc iodide, 0.5M in tetrahydrofuran 749928-54-9 AB 391153 2-Bromo-3-hexylthiophen-5-ylzinc bromide; 0.5 M in THF 144634-74-2 Br Zn Br Br Br Zn Br I Zn F Zn I Br Br Zn F F Br F Br I Zn F Br Zn S Br Gute Chemie

Gute Chemie. New Organozinc Reagents 9 AB 361362 5-Bromo-2-methoxybenzylzinc chloride, 0.5M in tetrahydrofuran 352530-35-9 Br O AB 361463 2-Bromo-4,5-(Methylenedioxy)benzylzinc bromide, 0.5M in tetrahydrofuran AB 361425 4-Bromo-2-methylphenylzinc iodide, 0.5M in tetrahydrofuran 1141981-37-4 AB 361426 4-Bromo-3-methylphenylzinc iodide, 0.5M in tetrahydrofuran 1142219-89-3 AB 361470 3-Bromophenethylzinc bromide, 0.5M in tetrahydrofuran AB 361469 4-Bromophenethylzinc bromide, 0.5M in tetrahydrofuran 2241502-60-1 AB 356146 3-Bromophenylzinc iodide, 0.5M in THF 186000-44-2 AB 356041 4-Bromophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 148651-39-2 AB 361375 3-Bromo-2-thienylzinc bromide, 0.5M in tetrahydrofuran 672325-70-1 AB 356219 5-Bromo-2-thienylzinc bromide, 0.5M in THF 151073-94-8 AB 348300 3-Butenylzinc bromide, 0.5M in THF 226570-67-8 AB 361421 4-tert-Butoxy-4-oxobutylzinc bromide, 0.5M in tetrahydrofuran 1142218-21-0 Zn Cl Br Zn Br Zn I Br Br Br O O Br Zn I Zn Br Zn Br Zn I Br Zn I Br S Br Zn Br Br S Br Zn Zn Br O O Zn Br abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

10 AB 361316 2-tert-Butoxy-2-oxoethylzinc chloride, 0.5M in Diethyl Ether 321745-86-2 AB 361423 6-tert-Butoxy-6-oxohexylzinc bromide, 0.5M in tetrahydrofuran 1141980-62-2 AB 361486 2-tert-Butoxy-2-oxo-1-methylethylzinc bromide, 0.5M in Diethyl Ether 51656-71-4 AB 361422 5-tert-Butoxy-5-oxopentylzinc bromide, 0.5M in tetrahydrofuran AB 361420 3-tert-Butoxy-3-oxopropylzinc bromide, 0.5M in tetrahydrofuran 1142217-00-2 AB 361384 4-tert-Butylbenzylzinc bromide, 0.5M in tetrahydrofuran 737797-48-7 AB 349479 n-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 92273-73-9 AB 356158 sec-Butylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 171860-66-5 AB 349637 tert-Butylzinc bromide, 0.5M in THF 7565-59-5 AB 347894 2-Chlorobenzylzinc chloride, 0.5M in THF 312624-11-6 AB 356166 3-Chlorobenzylzinc chloride, 0.5M in THF 312624-13-8 AB 356086 4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 149923-10-4 Gute Chemie O Zn Cl O O O Zn Br O Zn Br O O O Br Zn O O Br Zn Br Zn Zn Br Zn Br Br Zn Cl Zn Cl Cl Cl Zn Cl Zn Cl

Gute Chemie. New Organozinc Reagents 11 AB 348496 4-Chlorobutylzinc bromide, 0.5M in THF 155589-48-3 AB 228358 2-Chloro-6-ﬂuorobenzylzinc chloride; 0.5 M in THF 307531-98-2 AB 361453 3-Chloro-4-ﬂuorobenzylzinc chloride, 0.5M in tetrahydrofuran Cl Br Zn F Zn Cl Cl Zn Cl Cl F AB 361454 3-Chloro-5-ﬂuorobenzylzinc chloride, 0.5M in tetrahydrofuran 1927897-12-8 Cl Cl Zn AB 361455 4-Chloro-3-ﬂuorobenzylzinc chloride, 0.5M in tetrahydrofuran F Cl Zn F Cl AB 361429 3-Chloro-5-ﬂuorophenethylzinc bromide, 0.5M in tetrahydrofuran 1142220-73-2 Cl AB 229097 4-Chloro-3-ﬂuorophenylzinc bromide; 0.50 M in THF 473694-19-8 AB 231921 2-Chloro-4-ﬂuorophenylzinc iodide; 0.5 M in THF 497923-83-8 AB 356867 3-Chloro-4-ﬂuorophenylzinc iodide, 0.5M in THF 312624-19-4 AB 231588 4-Chloro-2-ﬂuorophenylzinc iodide; 0.5M solution in THF 518989-99-6 AB 361323 4-Chloro-3-ﬂuorophenylzinc iodide, 0.5M in tetrahydrofuran 312693-42-8 AB 348702 6-Chlorohexylzinc bromide, 0.5M in THF 135579-83-8 Br Zn F F Cl F Cl F Cl I Zn Zn Br I Zn Cl Zn I I Zn F Cl F Cl Zn Br abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

12 AB 361442 4-Chloro-2-Methoxycarbonylphenylzinc bromide, 0.5M in tetrahydrofuran AB 361471 5-Chloro-2-methoxyphenylzinc bromide, 0.5M in tetrahydrofuran Cl O Zn Br O Cl O Zn Br AB 361376 5-Chloro-2-methoxyphenylzinc iodide, 0.5M in tetrahydrofuran 737797-36-3 Cl AB 361449 4-Chloro-2-methylbenzylzinc chloride, 0.5M in tetrahydrofuran 775329-42-5 Cl Zn I Zn O AB 361450 4-Chloro-3-methylbenzylzinc chloride, 0.5M in tetrahydrofuran AB 361377 2-Chloro-6-methylphenylzinc iodide, 0.5M in tetrahydrofuran 737797-38-5 Cl Zn Cl I Zn AB 361340 3-Chloro-4-methylphenylzinc iodide, 0.5M in tetrahydrofuran 352525-66-7 Zn I Cl Cl Cl AB 356224 5-Chloropentylzinc bromide, 0.5M in THF 312624-21-8 AB 361408 3-Chlorophenethylzinc bromide, 0.5M in tetrahydrofuran 1141978-48-4 AB 361407 4-Chlorophenethylzinc bromide, 0.5M in tetrahydrofuran 1142215-67-5 AB 391202 [3-(4-Chlorophenyl)prop-1-en-2-yl]zinc iodide; 0.5 M in THF Cl Br Zn Br Zn Br Zn Zn I Cl Cl Cl Gute Chemie

Gute Chemie. New Organozinc Reagents 13 AB 356024 2-Chlorophenylzinc iodide, 0.5M in THF 148651-35-8 AB 356155 3-Chlorophenylzinc iodide, 0.5M in THF 186000-42-0 AB 356163 4-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 151073-70-0 AB 361373 (2-Chloro-5-pyridyl)methylzinc chloride, 0.5M in tetrahydrofuran 352530-36-0 AB 361477 2-Chloro-3-pyridylzinc bromide, 0.5M in tetrahydrofuran 1227833-83-1 AB 361478 2-Chloro-4-pyridylzinc bromide, 0.5M in tetrahydrofuran 1227940-97-7 AB 361466 2-Chloro-5-pyridylzinc bromide, 0.5M in tetrahydrofuran 1227833-84-2 AB 361479 6-Chloro-2-pyridylzinc bromide, 0.5M in tetrahydrofuran AB 356141 5-Chloro-2-thienylzinc bromide, 0.5M in THF 312624-22-9 Cl Zn I Zn I Cl Zn I Cl Cl Zn N Cl N Br Zn Cl Zn Br Cl N Cl N Br Zn Cl N Zn Br Cl S Br Zn AB 361484 4-Coumarinylzinc bromide, 0.5M in tetrahydrofuran 1330062-40-2 O O AB 361324 2-Cyanobenzylzinc bromide, 0.5M in tetrahydrofuran 199465-66-2 AB 361325 3-Cyanobenzylzinc bromide, 0.5M in tetrahydrofuran 117269-72-4 Zn Br Zn Br N Zn Br N abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

14 AB 361326 4-Cyanobenzylzinc bromide, 0.5M in tetrahydrofuran 135579-87-2 AB 356206 4-Cyanobutylzinc bromide, 0.5M in THF 226570-68-9 AB 356150 2-Cyanoethylzinc bromide, 0.5M in THF 312624-26-3 AB 231752 2-Cyano-3-ﬂuorophenylzinc iodide; 0.5M solution in THF 352525-67-8 AB 231589 3-Cyano-4-ﬂuorophenylzinc bromide; 0.5 M in THF 518990-00-6 AB 231290 4-Cyano-3-ﬂuorophenylzinc bromide; 0.5 M in THF 521093-90-3 AB 348706 6-Cyanohexylzinc bromide, 0.5M in THF 312624-28-5 AB 361329 5-Cyano-5-methylhexylzinc bromide, 0.5M in tetrahydrofuran 312693-22-4 AB 348108 2-Cyanophenylzinc bromide, 0.5M in THF 131379-17-4 AB 348541 4-Cyanophenylzinc bromide, 0.5M in THF 131379-14-1 AB 361318 3-Cyanophenylzinc iodide, 0.5M in tetrahydrofuran 288309-53-5 AB 361319 4-Cyanophenylzinc iodide, 0.5M in tetrahydrofuran 220213-92-3 Gute Chemie Br Zn Br Zn N N Zn Br N N F N N F F Zn I Zn Br Br Zn Zn Br Zn Br N N N Zn Br Zn Br I Zn I Zn N N N

Gute Chemie. New Organozinc Reagents 15 AB 356225 3-Cyanopropylzinc bromide, 0.5M in THF 135579-85-0 AB 361435 5-Cyanovalerylzinc bromide, 0.5M in tetrahydrofuran 1443250-11-0 AB 361438 Cyclobutylzinc bromide, 0.5M in tetrahydrofuran 1019205-65-2 AB 361428 2-Cyclohexylethylzinc bromide, 0.5M in tetrahydrofuran 1010684-05-5 Br Zn Zn Br N N Br Zn Zn Br AB 347598 (Cyclohexylmethyl)zinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 135579-86-1 Br Zn AB 356195 Cyclohexylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 7565-57-3 AB 348937 Cyclopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable bottles 126403-68-7 AB 391186 1-Decen-2-ylzinc iodide; 0.5 M in THF Br Zn Zn Br Zn I AB 349497 n-Decylzinc bromide, 0.5M in THF 160516-17-6 AB 361355 2,4-Dichlorobenzylzinc chloride, 0.5M in tetrahydrofuran 737797-16-9 AB 361357 2,5-Dichlorobenzylzinc chloride, 0.5M in tetrahydrofuran 737797-20-5 AB 173642 2,6-Dichlorobenzylzinc chloride, 0.5M in THF 307531-80-2 Br Zn Cl Cl Cl Zn Cl Zn Cl Cl Cl Cl Zn Cl abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

16 AB 361356 3,4-Dichlorobenzylzinc chloride, 0.5M in tetrahydrofuran 737797-18-1 Zn Cl AB 361418 3,5-Dichlorobenzylzinc chloride, 0.5M in tetrahydrofuran 352530-34-8 Cl AB 361487 3,4-Dichlorophenethylzinc bromide, 0.5M in tetrahydrofuran Zn Cl Cl Cl Cl Cl Cl Zn Br AB 356095 2,3-Dichlorophenylzinc iodide, 0.5M in THF 307531-97-1 Cl Cl AB 356134 2,4-Dichlorophenylzinc iodide, 0.5M in THF 352530-42-8 AB 356108 2,5-Dichlorophenylzinc iodide, 0.5M in THF 352530-43-9 AB 356101 3,4-Dichlorophenylzinc iodide, 0.5M in THF 312692-85-6 AB 348262 3,5-Dichlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 312692-86-7 AB 361430 (Diethoxyphosphoryl)diﬂuoromethylzinc bromide, 0.5M in tetrahydrofuran 82845-20-3 AB 122307 Diethylzinc; 95% 557-20-0 AB 304120 Diethylzinc; 95%, contained in 50 ml Swagelok cylinder for CVD/ALD 557-20-0 AB 355965 Diethylzinc; 95%, contained in high-temp. 50 ml Swagelok cylinder for CVD/ALD 557-20-0 Gute Chemie Zn I Cl Zn I Cl Zn I Zn Zn I I Cl Cl Cl Cl Cl Cl F F O O P O Zn Br Zn Zn Zn

Gute Chemie. New Organozinc Reagents 17 AB 131614 Diethylzinc; 95%, 10 wt% in hexane 557-20-0 AB 122308 Diethylzinc, elec. gr.; (99.9998% Zn) PURATREM, steel cylinder extra 557-20-0 AB 352757 2,4-Diﬂuorobenzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 307496-26-0 AB 356892 2,5-Diﬂuorobenzylzinc bromide, 0.5M in THF 307496-32-8 AB 356888 2,6-Diﬂuorobenzylzinc bromide, 0.5M in THF 307496-33-9 AB 353007 3,4-Diﬂuorobenzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 307496-34-0 AB 230795 3,5-Diﬂuorobenzylzinc bromide; 0.5 M in THF 308796-30-7 AB 361396 2,5-Diﬂuorobenzylzinc chloride, 0.5M in tetrahydrofuran 312692-89-0 AB 361397 3,5-Diﬂuorobenzylzinc chloride, 0.5M in tetrahydrofuran 352525-71-4 AB 361472 2,5-Diﬂuoro-4-methoxyphenylzinc bromide, 0.5M in tetrahydrofuran AB 391201 [3-(3,5-Diﬂuorophenyl)prop-1-en-2-yl]zinc iodide; 0.5 M in THF Zn Zn F Zn Br Zn Br F F Br Zn F Br Zn Br Zn F F F F F F F Cl Zn F F F F Br Zn Zn Cl F O Zn I F F abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

18 AB 356587 2,3-Diﬂuorophenylzinc bromide, 0.5M in THF AB 356900 2,4-Diﬂuorophenylzinc bromide, 0.5M in THF 517920-79-5 AB 361443 2,5-Diﬂuorophenylzinc bromide, 0.5M in tetrahydrofuran AB 361440 2,6-Diﬂuorophenylzinc bromide, 0.5M in tetrahydrofuran 1380918-98-8 AB 356879 3,5-Diﬂuorophenylzinc bromide, 0.5M in THF 307531-85-7 AB 232425 3,4-Diﬂuorophenylzinc bromide, 0.5M in THF 737797-28-3 Br Zn F F F F F Br Zn F Zn Br F Zn Br F F F F F Br Zn Zn Br AB 361359 2,3-Dimethoxybenzylzinc chloride, 0.5M in tetrahydrofuran 737797-22-7 Zn Cl AB 361361 2,5-Dimethoxybenzylzinc chloride, 0.5M in tetrahydrofuran 352530-32-6 AB 361360 3,4-Dimethoxybenzylzinc chloride, 0.5M in tetrahydrofuran 307531-79-9 AB 361363 3,5-Dimethoxybenzylzinc chloride, 0.5M in tetrahydrofuran 352530-33-7 AB 361389 2,5-Dimethoxyphenylzinc iodide, 0.5M in tetrahydrofuran 738580-37-5 Gute Chemie O O O O O O Cl Zn Zn Cl Zn Cl O O O O Zn I

Gute Chemie. New Organozinc Reagents 19 AB 361390 3,4-Dimethoxyphenylzinc iodide, 0.5M in tetrahydrofuran 738580-38-6 AB 361427 3,5-Dimethoxyphenylzinc Iodide, 0.5M in tetrahydrofuran 2246939-72-8 AB 361327 3,5-Dimethyl-1-adamantylzinc bromide, 0.5M in tetrahydrofuran 312692-99-2 O O O I Zn O I Zn Zn Br H2 C H2 C CH2 AB 391203 {3-[3-(Dimethylamino)phenyl]prop-1-en-2-yl}zinc iodide; 0.5 M in THF AB 391204 {3-[4-(Dimethylamino)phenyl]prop-1-en-2-yl}zinc iodide; 0.5 M in THF AB 361367 3,5-Dimethylbenzylzinc bromide, 0.5M in tetrahydrofuran 937818-32-1 AB 361391 2,4-Dimethylbenzylzinc chloride, 0.5M in tetrahydrofuran Zn I Zn I AB 361366 2,5-Dimethylbenzylzinc chloride, 0.5M in tetrahydrofuran 737797-24-9 Cl Zn AB 361419 3,4-Dimethylbenzylzinc chloride, 0.5M in tetrahydrofuran AB 361441 3,5-Dimethyl-4-methoxyphenethylzinc bromide, 0.5M in tetrahydrofuran AB 361335 2,3-Dimethylphenylzinc iodide, 0.5M in tetrahydrofuran 312692-94-7 Zn Cl O I Zn N N Zn Br Zn Cl Zn Br abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

20 AB 347827 2,4-Dimethylphenylzinc iodide, 0.5M in THF 312692-95-8 AB 356129 2,5-Dimethylphenylzinc iodide, 0.5M in THF 312692-96-9 AB 361336 2,6-Dimethylphenylzinc iodide, 0.5M in tetrahydrofuran 282727-21-3 AB 348260 3,4-Dimethylphenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 312692-97-0 Zn I Zn I I Zn Zn I AB 348266 3,5-Dimethylphenylzinc iodide, 0.5M in THF 312692-98-1 Zn I AB 121692 Dimethylzinc; 99% 544-97-8 AB 333981 Dimethylzinc; 99%, contained in 50 ml Swagelok cylinder for CVD/ALD 544-97-8 AB 122309 Dimethylzinc, elec. gr.; (99.999% Zn) PURATREM 544-97-8 AB 333982 Dimethylzinc; elec. gr. (99.999%-Zn) PURATREM, 97-5060 544-97-8 AB 130804 Dimethylzinc; 99% (10 wt% in hexane), Sure/Seal bottle 544-97-8 AB 356210 2-(1,3-Dioxan-2-yl)ethylzinc bromide, 0.5M in THF 307531-82-4 AB 361353 2-(1,3-Dioxolan-2-yl)ethylzinc bromide, 0.5M in THF 307531-83-5 Gute Chemie Zn Zn Zn Zn Zn O O O O Br Zn Zn Br

Gute Chemie. New Organozinc Reagents 21 AB 361481 5-(1,3-Dioxolan-2-yl)-2-furylzinc bromide, 0.5M in tetrahydrofuran 1276045-68-1 AB 361437 (1,3-Dioxolan-2-ylmethyl)zinc bromide, 0.5M in tetrahydrofuran 1135389-59-1 AB 361354 5-(1,3-Dioxolan-2-yl)-2-thienylzinc bromide, 0.5M in tetrahydrofuran 307531-84-6 AB 122310 Diphenylzinc; 99% 1078-58-6 O O O Zn Br O O Br Zn H O S Zn Br O Zn AB 356118 n-Dodecylzinc bromide, 0.5M in THF 869589-06-0 Zn I AB 361349 2-Ethoxybenzylzinc chloride, 0.5M in tetrahydrofuran 308796-28-3 AB 361350 4-Ethoxybenzylzinc chloride, 0.5M in tetrahydrofuran 308796-29-4 AB 348406 4-(Ethoxycarbonyl)butylzinc bromide, 0.5M in THF 265330-98-1 AB 212313 2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF 193065-68-8 AB 361371 5-Ethoxycarbonylfurfurylzinc chloride, 0.5M in tetrahydrofuran 352530-38-2 AB 361383 5-Ethoxycarbonyl-2-furylzinc bromide, 0.5M in tetrahydrofuran 307531-81-3 AB 348648 5-(Ethoxycarbonyl)pentylzinc bromide, 0.5M in THF 312693-01-9 Zn Cl O Cl Zn O O Zn Br O O O O Cl Zn Zn O Br Zn Br O O O O O O Br Zn abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

22 AB 356159 2-(Ethoxycarbonyl)phenylzinc bromide, 0.5M in THF 131379-40-3 O O Zn Br AB 356061 4-(Ethoxycarbonyl)phenylzinc bromide, 0.5M in THF 131379-15-2 AB 348230 3-(Ethoxycarbonyl)phenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 282727-18-8 AB 361317 4-Ethoxycarbonylphenylzinc iodide, 0.5M in tetrahydrofuran 131379-16-3 I Zn AB 348231 3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF 131379-39-0 O O O O AB 361382 5-Ethoxycarbonyl-2-thienylzinc bromide, 0.5M in tetrahydrofuran 352530-37-1 AB 361433 7-Ethoxy-7-oxoheptylzinc bromide, 0.5M in tetrahydrofuran 1370594-13-0 AB 361434 8-Ethoxy-8-oxooctylzinc bromide, 0.5M in tetrahydrofuran AB 356087 1-Ethylbutylzinc bromide, 0.5M in THF 312693-14-4 O O Zn S Br O O O O AB 348126 2-Ethylbutylzinc bromide, 0.5M in THF 312693-02-0 Br Zn AB 348127 2-Ethylhexylzinc bromide, 0.5M in THF 312693-03-1 AB 356197 1-Ethylpentylzinc bromide, 0.5M in THF 312693-11-1 Br Zn Zn I Br Zn O O O O Zn Br Br Zn Zn Br Br Zn Zn Br Gute Chemie

Gute Chemie. New Organozinc Reagents 23 AB 348129 2-Ethylphenylzinc iodide, 0.5M in THF 282727-19-9 I Zn AB 356216 4-Ethylphenylzinc iodide, 0.5M in THF 312693-04-2 I Zn AB 347762 1-Ethylpropylzinc bromide, 0.5M in THF 308796-09-0 AB 231908 2-Fluorobenzylzinc chloride 0.5 M in THF 312693-05-3 F AB 232937 3-Fluorobenzylzinc chloride, 0.5M in THF 312693-06-4 AB 356889 4-Fluorobenzylzinc chloride, 0.5M in THF 312693-07-5 AB 361451 3-Fluoro-4-methoxybenzylzinc chloride, 0.5M in tetrahydrofuran 1839069-73-6 AB 361452 5-Fluoro-2-methoxybenzylzinc chloride, 0.5M in tetrahydrofuran AB 361444 3-Fluoro-2-methylbenzylzinc chloride, 0.5M in tetrahydrofuran AB 361445 3-Fluoro-4-methylbenzylzinc chloride, 0.5M in tetrahydrofuran AB 361446 4-Fluoro-2-methylbenzylzinc chloride, 0.5M in tetrahydrofuran AB 361447 4-Fluoro-3-methylbenzylzinc chloride, 0.5M in tetrahydrofuran F F Cl Zn F Cl Zn Cl Zn F Cl Zn Zn Br Cl Zn Cl Zn Cl Zn F O Zn Cl O F F Zn Cl F abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

24 AB 361448 5-Fluoro-2-methylbenzylzinc chloride, 0.5M in tetrahydrofuran F Zn Cl AB 232944 2-Fluoro-4-methylphenylzinc bromide; 0.5M solution in THF 737797-14-7 AB 356681 5-Fluoro-2-methylphenylzinc bromide, 0.5M in THF 672325-66-5 AB 356880 3-Fluoro-4-methylphenylzinc iodide, 0.5M in THF 312693-08-6 AB 232938 4-Fluoro-3-methylphenylzinc iodide; 0.50 M in THF 352525-72-5 AB 230798 5-Fluoro-2-methylphenylzinc iodide; 0.5 M in THF 312693-09-7 AB 361467 2-Fluorophenethylzinc bromide, 0.5M in tetrahydrofuran 1800201-42-6 AB 361410 3-Fluorophenethylzinc bromide, 0.5M in tetrahydrofuran 1142275-36-2 AB 361409 4-Fluorophenethylzinc bromide, 0.5M in tetrahydrofuran 1029128-52-6 AB 391190 [4-(2-Fluorophenyl)but-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391191 [4-(3-Fluorophenyl)but-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391192 [4-(4-Fluorophenyl)but-1-en-2-yl]zinc iodide; 0.5 M in THF Gute Chemie Br Zn F F Zn Br F Zn I I Zn I Zn Br Zn F F F F F F F F Br Zn Br Zn I Zn I Zn I Zn

Gute Chemie. New Organozinc Reagents 25 AB 391195 [3-(3-Fluorophenyl)prop-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391196 [3-(4-Fluorophenyl)prop-1-en-2-yl]zinc iodide; 0.5 M in THF AB 356882 4-Fluorophenylzinc bromide, 0.5M in THF 181705-93-1 Zn Zn I I F F F Br Zn AB 352887 2-Fluorophenylzinc iodide, 0.5M in THF 186000-41-9 F Zn I AB 353140 3-Fluorophenylzinc iodide, 0.5M in THF 307496-28-2 AB 361476 5-Fluoro-2-pyridylzinc bromide, 0.5M in tetrahydrofuran 935433-87-7 AB 361351 1-Heptylzinc bromide, 0.5M in tetrahydrofuran 7608-06-2 AB 361352 1-Hexadecylzinc bromide, 0.5M in tetrahydrofuran 737797-10-3 Zn Br AB 356122 5-Hexenylzinc bromide, 0.5M in THF 226570-65-6 AB 356025 n-Hexylzinc bromide, 0.5M in THF 124397-96-2 AB 361372 2-Iodobenzylzinc bromide, 0.5M in tetrahydrofuran 117269-71-3 AB 361358 3-Iodobenzylzinc bromide, 0.5M in tetrahydrofuran 352530-31-5 F Zn I Br Zn F N Zn Br Br Zn Br Zn Zn Br I Zn Br I abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

26 AB 361365 4-Iodobenzylzinc bromide, 0.5M in tetrahydrofuran 352530-30-4 AB 349124 Isobutylzinc bromide, 0.5 M in THF 126403-67-6 AB 356043 Isopentylzinc bromide, 0.5M in THF 92274-43-6 AB 361338 2-iso-Propylphenylzinc iodide, 0.5M in tetrahydrofuran 308796-17-0 AB 361330 4-iso-Propylphenylzinc iodide, 0.5M in tetrahydrofuran 308796-20-5 AB 356088 Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 77047-87-1 AB 361459 4-Isoquinolinzinc bromide, 0.5M in tetrahydrofuran 1207760-37-9 AB 361364 (R)-(+)-3-Methoxy-2-methyl-3-oxopropylzinc bromide, 0.5M in tetrahydrofuran 343338-26-1 AB 361320 3-Methoxy(2S)-(-)-methyl-3-oxopropylzinc bromide, 0.5M in tetrahydrofuran 312693-18-8 AB 361343 2-Methoxybenzylzinc chloride, 0.5M in tetrahydrofuran 312693-15-5 AB 361331 3-Methoxybenzylzinc chloride, 0.5M in tetrahydrofuran 312693-16-6 AB 361344 4-Methoxybenzylzinc chloride, 0.5M in tetrahydrofuran 312693-17-7 Gute Chemie Br Zn I Zn Br Br Zn I Zn I Zn Br Zn Zn Br N H Br Zn Br Zn Zn Cl O O O O H O Zn Cl Cl Zn O O

Gute Chemie. New Organozinc Reagents 27 AB 361416 2-Methoxyphenethylzinc bromide, 0.5M in tetrahydrofuran AB 361415 3-Methoxyphenethylzinc bromide, 0.5M in tetrahydrofuran 1142232-31-2 AB 361414 4-Methoxyphenethylzinc bromide, 0.5M in tetrahydrofuran 1800201-43-7 AB 391193 [4-(3-Methoxyphenyl)but-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391194 [4-(4-Methoxyphenyl)but-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391197 [3-(3-Methoxyphenyl)prop-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391198 [3-(4-Methoxyphenyl)prop-1-en-2-yl]zinc iodide; 0.5 M in THF AB 348187 2-Methoxyphenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 282727-20-2 AB 356233 3-Methoxyphenylzinc iodide, 0.5M in THF 300825-30-3 AB 356148 4-Methoxyphenylzinc iodide, 0.5M in THF 254454-47-2 AB 361374 6-Methoxy-2-pyridylzinc bromide, 0.5M in tetrahydrofuran 352530-39-3 AB 391154 6-Methyl-2H-2-oxopyran-4-ylzinc bromide; 0.5M in THF O Zn Br Br Zn Br Zn O O O O I Zn I Zn Zn O I I Zn O O Zn I Zn I O Zn I O Br Zn N O Zn Br O O abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

28 AB 361345 2-Methylbenzylzinc chloride, 0.5M in tetrahydrofuran 312693-19-9 AB 361346 3-Methylbenzylzinc chloride, 0.5M in tetrahydrofuran 312693-20-2 AB 361347 4-Methylbenzylzinc chloride, 0.5M in tetrahydrofuran 312693-21-3 AB 348762 alpha-Methylbenzylzinc chloride, 0.5M in THF 85459-20-7 AB 347767 1-Methylbutylzinc bromide, 0.5M in THF 308796-07-8 AB 361464 3,4-(Methylenedioxy)phenylzinc iodide, 0.5M in tetrahydrofuran 1357013-37-6 AB 356204 1-Methylhexylzinc bromide, 0.5M in THF 312693-10-0 AB 356091 1-Methylpentylzinc bromide, 0.5M in THF 312693-13-3 AB 361413 2-Methylphenethylzinc bromide, 0.5M in tetrahydrofuran AB 361412 3-Methylphenethylzinc bromide, 0.5M in tetrahydrofuran 1142231-40-0 Zn Cl Cl Zn O O AB 361411 4-Methylphenethylzinc bromide, 0.5M in tetrahydrofuran Zn Br AB 391187 [4-(2-Methylphenyl)but-1-en-2-yl]zinc iodide; 0.5 M in THF Gute Chemie Zn Cl Zn Cl Zn Br Zn I Zn Br Zn Br Br Zn Zn Br I Zn

Gute Chemie. New Organozinc Reagents 29 AB 391188 [4-(3-Methylphenyl)but-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391189 [4-(4-Methylphenyl)but-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391199 [3-(3-Methylphenyl)prop-1-en-2-yl]zinc iodide; 0.5 M in THF AB 391200 [3-(4-Methylphenyl)prop-1-en-2-yl]zinc iodide; 0.5 M in THF AB 356165 2-Methylphenylzinc iodide, 0.5M in THF 312693-23-5 AB 356042 3-Methylphenylzinc iodide, 0.5M in THF 312693-24-6 AB 348598 4-Methylphenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 300766-53-4 AB 361465 2-Methyl-4-pyridylzinc bromide, 0.5M in tetrahydrofuran 1115492-92-6 AB 361462 2-Methyl-5-pyridylzinc bromide, 0.5M in tetrahydrofuran 1227833-82-0 AB 361342 3-Methyl-2-pyridylzinc bromide, 0.5M in tetrahydrofuran 308795-91-7 AB 361341 4-Methyl-2-pyridylzinc bromide, 0.5M in tetrahydrofuran 308795-93-9 AB 361461 4-Methyl-3-pyridylzinc bromide, 0.5M in tetrahydrofuran 1227833-81-9 I Zn I Zn Zn Zn I I Zn I Zn I I Zn Zn Br N Zn Br N N Br Zn N Br Zn Zn Br N abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

30 AB 356128 5-Methyl-2-pyridylzinc bromide, 0.5M in THF 257876-05-4 AB 348708 6-Methyl-2-pyridylzinc bromide, 0.5M in THF 308795-98-4 AB 361348 3-Methyl-2-thienylzinc bromide, 0.5M in tetrahydrofuran 312693-45-1 AB 361424 5-Methyl-2-thienylzinc bromide, 0.5M in tetrahydrofuran 1233318-32-5 AB 348407 4-(Methylthio)phenylzinc iodide, 0.5M in THF 307496-24-8 AB 361398 2-[(4-Morpholino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran AB 361399 3-[(4-Morpholino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran 1142212-14-3 AB 361400 4-[(4-Morpholino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran 1141977-27-6 AB 361332 (2-Naphthyl)methylzinc bromide, 0.5M in tetrahydrofuran 152329-44-7 AB 361482 (1-Naphthyl)methylzinc chloride, 0.5M in tetrahydrofuran 1372433-71-0 AB 361339 1-Naphthylzinc iodide, 0.5M in tetrahydrofuran 46000-10-6 AB 361439 Neopentylzinc bromide, 0.5M in tetrahydrofuran 676137-12-5 Gute Chemie Br Zn N Br Zn N S Br Zn S Zn Br I Zn S I Zn N O N N O O Br Zn Zn Cl Zn I I I Zn Zn Zn Br

Gute Chemie. New Organozinc Reagents 31 AB 361417 Neopentylzinc iodide, 0.5M in tetrahydrofuran 262422-94-6 AB 356117 n-Nonylzinc bromide, 0.5M in THF 626207-32-7 AB 361328 exo-2-Norbornylzinc bromide, 0.5M in tetrahydrofuran 342029-20-3 AB 361432 n-Octadecylzinc bromide, 0.5M in tetrahydrofuran 1142222-21-6 Zn Br AB 356049 n-Octylzinc bromide, 0.5M in THF 131379-13-0 AB 229101 Pentaﬂuorobenzylzinc bromide; 0.50 M in THF 352534-75-9 AB 348628 4-Pentenylzinc bromide, 0.5M in THF 308796-04-5 AB 361321 4-n-Pentylphenylzinc iodide, 0.5M in tetrahydrofuran 308796-05-6 AB 356126 n-Pentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 308796-10-3 AB 349638 tert-Pentylzinc bromide, 0.5M in THF 171860-64-3 Zn Br AB 361337 9-Phenanthrenylzinc iodide, 0.5M in tetrahydrofuran 308796-12-5 Zn I Br Zn H Zn Br Zn Br F F F F Br Zn F Br Zn I Zn Br Zn Zn I abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

32 AB 361370 4-Phenoxybutylzinc bromide, 0.5M in tetrahydrofuran 737797-32-9 AB 361369 3-Phenoxypropylzinc bromide, 0.5M in tetrahydrofuran 626207-36-1 AB 361368 4-Phenylbenzylzinc chloride, 0.5M in tetrahydrofuran 595610-22-3 O Zn Br O Br Zn AB 361468 Phenyl-1,4-di(methylzinc chloride), 0.5M in tetrahydrofuran AB 348198 2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 308796-14-7 AB 356102 3-Phenylpropylzinc bromide, 0.5M in THF 626207-42-9 AB 356136 Phenylzinc bromide, 0.5M in THF 38111-44-3 AB 349563 Phenylzinc iodide, 0.5M in THF 23665-09-0 AB 361404 2-[(1-Piperidino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran 1263144-74-6 AB 361405 3-[(1-Piperidino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran 1142213-96-4 AB 361406 4-[(1-Piperidino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran AB 347770 1-Propylbutylzinc bromide, 0.5M in THF 312693-12-2 Gute Chemie Cl Zn Cl Zn Br Zn Zn Cl Br Zn Br Zn I Zn I Zn N I I Zn Zn N N Zn Br

Gute Chemie. New Organozinc Reagents 33 AB 349535 n-Propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 156567-57-6 AB 361480 2-Pyridinylmethyl zinc chloride, 0.5M in THF 165334-81-6 AB 356844 2-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 218777-23-2 AB 361457 3-Pyridylzinc bromide, 0.5M in tetrahydrofuran 220565-63-9 AB 361458 5-Pyrimidylzinc bromide, 0.5M in tetrahydrofuran 1227941-02-7 AB 361401 2-[(1-Pyrrolidino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran 1142273-97-9 AB 361402 3-[(1-Pyrrolidino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran 1142274-42-7 AB 361403 4-[(1-Pyrrolidino)methyl]phenylzinc iodide, 0.5M in tetrahydrofuran 1142274-84-7 AB 361460 3-Quinolylzinc bromide, 0.5M in tetrahydrofuran 1207760-36-8 AB 361322 a-Styrenylzinc bromide, 0.5M in tetrahydrofuran 151073-86-8 AB 361436 Tetradecylzinc bromide, 0.5M in tetrahydrofuran 1610827-42-3 Br Zn AB 361380 2,3,5,6-Tetramethylphenylzinc iodide, 0.5M in tetrahydrofuran 737797-44-3 Zn Br Zn Cl N Br N Zn Zn Br Zn Br N N N I Zn N I I Zn Zn N N Zn Br N Zn Br I Zn abcr GmbH ▪ Phone +49 721 95061 - 0 ▪ Fax +49 721 95061 - 80 ▪ info@abcr.com ▪ www.abcr.com

34 AB 356070 2-Thiazolylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles 173382-28-0 AB 356033 2-Thienylzinc bromide, 0.5M in THF 45438-80-0 AB 361388 3-Thienylzinc iodide, 0.5M in tetrahydrofuran 172035-85-7 AB 361334 2-(Thiomethyl)phenylzinc iodide, 0.5M in tetrahydrofuran 308796-24-9 AB 361475 2,4,5-Triﬂuorobenzylzinc bromide, 0.5M in tetrahydrofuran AB 361474 3,4,5-Triﬂuorobenzylzinc bromide, 0.5M in tetrahydrofuran 955381-38-1 AB 361385 3-Triﬂuoromethylbenzylzinc chloride, 0.5M in tetrahydrofuran 480438-42-4 AB 361386 4-Triﬂuoromethylbenzylzinc chloride, 0.5M in tetrahydrofuran 738580-34-2 Br Zn S N Zn Br S S Zn I I Zn S F Zn Br F F F F F Zn Cl Cl Zn Zn Br CF3 CF3 AB 361488 3-Triﬂuoromethylphenethylzinc bromide, 0.5M in tetrahydrofuran Zn Br CF3 AB 361395 3,4,5-Triﬂuorophenylzinc bromide, 0.5M in tetrahydrofuran 1241382-67-1 F Br Zn AB 361381 2,4,6-Trimethylphenylzinc iodide, 0.5M in tetrahydrofuran 718628-26-3 F F I Zn Gute Chemie

Gute Chemie. Greater diversity, choice and value. Make use of our e-papers to quickly and easily browse through our catalogues and flyers and search for products. All products listed in the e-papers are linked to the respective product detail page within our website where you will find further information. We can also send the catalogues and flyers by mail. Silicon Compounds Life Science Drug Design Fluorinated Compounds Organozinc Reagents Palladium Catalysts Aryne Precursors Freaky Amino Acids Catalysts Ligands Find 400,000 specialty chemicals in our webshop www.abcr.com abcr GmbH Germany +49 721 95061-0 info@abcr.com abcr swiss AG +41 41 7201882 info@abcr-swiss.ch abcr france SAS +33 4 7291 3100 info@abcr-france.fr abcr IRL Ltd. +353 56 7738971 info@abcr-irl.ie abcr UK Ltd. +44 161 8187062 info@abcr-uk.com LLC ABCR CHEMI RUS +7 495 9664181 info@abcr-russia.ru (R,R)-Catalyst (35 mol-%)MnO2 (3 eq.), Li2CO3 (2 eq.)PhCF3, 115 °C, 24 hup to 86% yield) (2 eq.)NNOSO2RHHNNHSO2Rup to 94% yield(S,S)-ligand (8 mol-%)THF, diglyme-20°CRalkylNN)(S,S)-ligand (8 mol-%)R1CF3R1+F3C(S,S)-ligand (8 mol-%THF, diglym-20°alkylCoI2 (10 mol-%)(S,S)-ligand (12 mol-%)THF, -80°CArylMgBrROup to 96% yield)ROArylalkylCo(S,S)-ligand (12 mol-%THF, -80°CROBralkyl+ArylMgBrup to 96% yieldONNOCuTfOOTfNNO(R,R)-Catalyst (35 mol-%)MnO2 (3 eq.), Li2CO3 (2 eq.)PhCF3, 115 °C, 24 hup to 86% yield) (2 eq.)NNOSO2RHHNNHSO2RR2(DME)NiCl2 (5 mol-%)(S,S)-ligand (6 mol-%)TMEDA (1.6 eq.)THF, 0°Cup to 94% yieldR (5 mol-%) (6 mol-%)R1FFNOR2R2ZnClR1+BrFFNOR2R2(DME)NiCl(S,S)-ligandTMEDA (1.6 eq.)THF, 0°Cup to 94% yield(DME)NiCl2 (6 mol-%)(S,S)-ligand (8 mol-%)THF, diglyme-20°CRalkylONNO)(S,S)-ligand (8 mol-%)R1alkylCF3ZnClR1+F3C(DME)NiCl(S,S)-ligand (8 mol-%THF, diglym-20°XalkylCoI2 (10 mol-%)(S,S)-ligand (12 mol-%)THF, -80°CArylMgBrROup to 96% yield)ROArylalkylCo(S,S)-ligand (12 mol-%THF, -80°CROBralkyl+ArylMgBrup to 96% yieldNNO(S,S)-ligandONNOCuTfOOTfNNOCO2RArORArOCONR2OR1R2ArRNNNRONRNNR2R1NNRTsNR1R2R1CO2R2ONR1R2R3NR1R2R3OORetc.OTfTMSCsFCO2RArORArOCONR2OR1R2ArRNNNRONRNNR2R1NNRTsNR1R2R1CO2R2ONR1R2R3NR1R2R3OORetc.MeCNrtCommercial Organofunctional Silanes for Diagnostics and Separation01Commercial Organofunctional Silanes for Diagnostics and Separation01Life ScienceNew Chirals for Drug DesignNNNN01Life ScienceNew Chirals for Drug DesignNNNN0101Available in bulk quantities Fluoro Organic Intermediates01Available in bulk quantities Fluoro Organic IntermediatesNew Organozinc Reagents for Organic Synthesis01New Organozinc Reagents for Organic Synthesis01Palladium catalysts for C-C and C-N coupling reactions01Palladium catalysts for C-C and C-N coupling reactions01

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